1, 3-dioxopentylene

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Hazardous Chemicals List (2015 edition)

1, 3-dioxopentylene

Chinese name 1, 3-dioxopentylene
Chinese synonyms 1, 3-dioxopentylene; Ethylene glycol formaldehyde; Dioxopentane; Dioxopentylene; 1, 3-dioxy-cyclopentane /1, 3-dioxy-pentacyclic /1, 3-dioxy-pentacyclic; 1, 3-dioxane (containing stabilizer triethylamine)(1, 3-dioxane); Trioxane; 1, 3-dioxane
English name 1, 3 - Dioxolane
English synonyms 1, 3 Dioxolan; 1, 3-dioxole, dihydro-; 1, 3 - dioxole, dihydro -; 1, 3 - dixolane; glycolmethyleneether; Methyleneglycolmethyleneether; 1, 3 - DIOXACYCLOPENTANE; 1, 3 - DIOXOLANE
CAS number The 646-06-0
Molecular formula C3H6O2
Molecular weight 74.08
The EINECS 211-463-5
Related category Alternative energy;Anhydrous solvent;Organic chemical industry;Ultra-dry solvent;Chemical reagents used in production;microorganism;Organic solvent;Materials science;electrolyte;Organic raw material;Organic chemical raw material;Chemical raw material -1;intermediate;Pharmaceutical intermediate;alkanes;Chemical intermediate;Dioxanes & Dioxolanes;Dioxolanes;Intermediates & Fine Chemicals;Pharmaceuticals;Alternative Energy;Anhydrous Solvents;Electrolytes;Materials Science;Organic Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Sure/Seal Bottles;ACS and Reagent Grade Solvents;Amber Glass Bottles;ReagentPlus;ReagentPlus Solvent Grade Products;Organic chemical raw material;Chemical raw material;Chemical raw materials - plastics;Inorganic acids;Ingredients;Chemical material;hydrocarbon;Bulk chemicals;Organic intermediate;Chemical engineering
Mol file 646-06-0.mol
Structural formula 1,3-二氧戊环 结构式

1, 3-dioxane properties

Fusing point -95 °C (lit.)
Boiling point 75-76 °C/1.013 hPa
density 1.06 g/mL at 25 °C (lit.)
Vapor density 2.6 (vs air)
Vapor pressure 70 mm Hg ( 20 °C)
Refractive index n 20/D 1.401 (lit.)
Flash point 35 °F
Storage condition Store at <= 20°C.
solubility 1000g/l soluble
form liquid
colour White to almost white
explosive limit 2.1 20.5% (V)
Water solubility SOLUBLE
BRN 102453
Exposure limit ACGIH: TWA 20 ppm
stability Storage below 4 ° C
InChIKey WNXJIVFYUVYPPR-UHFFFAOYSA-N
LogP -0.37 at 20℃
CAS database 646-06-0(CAS DataBase Reference)
NIST Chemical information 1, 3 - Dioxolane (646-06-0)
EPA Chemical information 1,3-Dioxolane (646-06-0)

Uses and synthesis methods of 1, 3-dioxopentylene

1, 3-dioxopentane is colorless and transparent liquid at room temperature and pressure, soluble in water, ethanol, ether, acetone. Its vapor and air can form an explosive mixture, which can cause combustion and explosion in case of open fire and high heat energy. The compound has no danger of polymerization, but is intolerant to oxidants and acids.
Chemical property
Colorless transparent liquid. The freezing point is -95℃, the boiling point is 78℃ (100 kpa), the relative density is 1.066 (15/4℃), the refractive index is 1.3974, and the flash point is 1℃. It is miscible with water, soluble in alcohol, ether and benzene. An azeotrope formed with water, with a boiling point of 70-73 ° C and a water content of 6.7%. It can decolorize bromine water.
use
The product is the second monomer of copolyformaldehyde, which is copolymerized with triformaldehyde in a ratio of 95:5 to produce copolyformaldehyde. The product is also used as a solvent, and is also a silk finishing agent and sealing adhesive.
use
It is mainly used as solvent and extractant of oil and fat, electrolytic solvent of lithium battery, chlorine-based solvent stabilizer, drug intermediate and so on
use

1, 3-dioxopentane is an excellent organic solvent, mainly used as solvent and extractant of oil and fat, electrolytic solvent of lithium battery, and chlorine-based solvent stabilizer.

use
Used as a solvent for low boiling point compounds and as an extractant for oils, waxes, dyes and fiber derivatives
Production method
It is obtained by the reaction of polyformaldehyde with ethylene glycol. Polyformaldehyde and ethylene glycol were put into the reactor at 1:1.25 molar ratio, and the reaction was carried out at 90-110℃ under atmospheric pressure with strong acid ion exchange resin as catalyst. The azeotrope at 70-74℃ is distilled from the top of the distillation column, and then distilled and purified after salting out with sodium chloride and dewatering with anhydrous calcium chloride. The 71-74℃ fraction is cut and the water is removed to 200ppm with molecular sieve to obtain the finished product. Another operation is to make polyformaldehyde and ethylene glycol in the presence of concentrated sulfuric acid reaction, salt out by sodium chloride, solid alkali drying, distillation to obtain the product. Raw material consumption quota: polyformaldehyde (93-95%) 750kg/t, ethylene glycol 200kg/t.
category
Flammable liquid
Toxicity classification
Poisoned
Acute toxicity
Oral - rat LD50: 3000 mg/kg; Oral - mouse LD50: 3200 mg/kg
Stimulus data
Skin - Rabbit 530 mg mild; Eyes - Rabbit 750 micrograms
Flammability hazard characteristics
Flammable in case of open fire, high temperature, oxidizer; Burning produces irritating smoke
Storage and transportation characteristics
Warehouse ventilation and low temperature drying; Store separately from oxidants and acids
Fire extinguishing agent
Dry powder, dry sand, carbon dioxide, foam, 1211 extinguishing agent
Professional standard
TWA 10 mg/m3; STEL 50 mg/m3

Safety information

Dangerous goods mark F
Hazard class code 11
Safety statement 16
Dangerous goods transport number UN 1166 3/PG 2
WGK Germany 1
The RTECS JH6760000
Spontaneous combustion temperature 525 °F
TSCA Yes
Danger class 3
Packaging category II
Customs code 29329970
Toxic substance data 646-06-0(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 3000 mg/kg LD50 dermal Rabbit 9074 mg/kg

MSDS Information

provider Language
Chinese
English
English
English
Chinese
English
Update date Product number Product name CAS number package Price
2024/04/30 042897 1, 3-diane, 99.5%, stab.
1,3-Dioxolane, 99.5%, stab.
The 646-06-0 250ml 373 yuan
2024/04/30 042897 1, 3-dioxane
1, 3 - Dioxolane
The 646-06-0 *4x1L 3465 yuan
"1, 3-dioxopentylene "related product information
Methylcyclopentane Diethylene glycol 1, 1-diethoxy ethane Ethylene oxide paraformaldehyde n-pentane cyclopentane Bromocyclopentane 2-methylbutane Diethylene glycol butyl ether Cyclopentadiene Ethylene glycol cyclopentanone Polyethylene glycol Selenium dioxide Ethylene glycol monobutyl ether polythene Sodium pentanesulfonate dioxopentycline 1, 3-dioxane
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